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Home  >Technical Resource  > Restriction Endonucleases pageTitle

DNA methyltransferases (MTases) are found in a wide variety of prokaryotes and eukaryotes. In prokaryotes, MTases have most often been identified as elements of restriction/modification systems in which they act to protect host DNA from cleavage by the corresponding restriction endonuclease. CpG MTases found in higher eukaryotes(e.g., Dnmt1) are not involved in restriction and modification. Nonetheless, patterns of CpG methylation are heritable, tissue specific, and correlate with gene expression. Consequently CpG methylation has been postulated to play a role in differentiation and gene expression (1). CpG methylase patterns can be approximated in vitro using the prokaryotic MTase, M.Sss I (NEB #M0226). 

We have screened a wide variety of restriction endonucleases whose recognition sites can be modified by M.Sss I in order to determine if cleavage is blocked by this modification. Three broad classes of enzymes were identified: (i) Those whose cleavage was completely blocked by modification, (ii) those whose cleavage was not blocked by modification, and (iii) those whose cleavage was blocked or impaired when the canonical restriction site overlapped the CG dinucleotide. The results are summarized below.

DNA modified by M.Sss I is restricted by McrA, McrBC, and Mrr systems in E. coli (2,3). Accordingly, DNAs which have been treated with M.Sss I should be transformed into Mcr- Mrr- strains, such as those available without charge from New England Biolabs.

In vivo methylation by M.Sss I has proven useful in overcoming methylation-based restriction during transformation (4) and in mapping chromatin structure in vivo (5).

References:
1. Siegfried, Z. and Cedar, H. (1997) Curr. Biol. 7, r305-307.
2. Kelleher, J.E. and Raleigh, E. (1991) J. Bacteriol. 173, 5220-5223.
3. Rees, P. et al. (1991) J. Bacteriol. 173, 5207-5219.
4. Butler, C.A. and Gotschlich, E.C. (1991) J. Bacteriol. 173, 5793-5799.
5. Kladde, M.P. and Simpson, R.T. (1996) Methods Enzymol. 274, 214-233.

Note:  Restriction enzyme cleavage is blocked when the recognition sequence is methylated by the cognate methylase. Methylation at other bases can block cleavage, leave cleavage unaffected or slow the rate or extent of cleavage. The rate of cleavage may also be affected by the DNA sequence flanking the recognition site. As a result, cleavage may depend on reaction conditions and on the site being studied, and cleavage of a substrate with multiple sites may yield a mixture of complete and partial digestion products. The accompanying tables should be viewed as a guide to the behavior of the enzymes listed rather than an absolute indicator. Consult REBASE<http://rebase.neb.com/rebase/>, the restriction enzyme database, for more detailed information and specific examples upon which these guidelines are based.

Footnotes:
1. Cleavage rate slowed significantly (impaired) by methylation.
2. Multiple overlaps required to block cleavage

Single Letter Code

Cleavage Blocked at All Sites
Aat II GACGTC
Aci I CCGC
Acl I AACGTT
Afe I AGCGCT
Age I ACCGGT
Asc I GGCGCGCC
AsiS I GCGATCGC
Ava I CYCGRG
BceA I ACGGC
BmgB I CACGTC
BsaA I YACGTR
BsaH I GRCGYC
BsiE I CGRYCG
BsiW I CGTACG
BsmB I CGTCTC
BspD I ATCGAT
BspE I1 TCCGGA
BsrB I1 CCGCTC
BsrF I RCCGGY
BssH II GCGCGC
BstB I TTCGAA
BstU I CGCG
Cla I ATCGAT
Eag I CGGCCG
Fau I CCCGC
Fse I GGCCGGCC
Fsp I TGCGCA
   
Hae II RGCGCY
Hga I GACGC
Hha I GCGC
HinP1 I GCGC
Hpa II CCGG
Hpy99 I CGWCG
HpyCH4 IV ACGT
Kas I GGCGCC
Mlu I ACGCGT
Nae I GCCGGC
Nar I GGCGCC
NgoM IV GCCGGC
Not I GCGGCCGC
   
Nru I TCGCGA
PaeR7 I1 CTCGAG
Pml I CACGTG
Pvu I CGATCG
Rsr II CGGWCCG
Sac II CCGCGG
Sal I GTCGAC
Sfo I GGCGCC
SgrA I CRCCGGYG
Sma I CCCGGG
SnaB I TACGTA
Til I1 CTCGAG
Xho I1 CTCGAG
   

Cleavage Blocked or Impaired Only at Sites with Overlapping CG
Acc I GTMKAC
Acc65 I GGTACC
Ahd I2 GAC(N5)GTC
Apa I GGGCCC
ApaL I GTGCAC
Ava II GGWCC
Bae I2 AC(N4)GTAYC
Ban I2 GGYRCC
Bcg I2 CGA(N6)TGC
BbvC I CCTCAGC
BfuA I ACCTGC
Bgl I2 GCC(N5)GGC
Bsa I GGTCTC
BsaB I1 GATN4ATC
Bsl I2 CCN7GG
BsmA I GTCTC
BsmF I GGGAC
BssK I CCNGG
BstAP I2 GCA(N5)TGC
BstZ I GTATAC
Cac8 I GCNNGC
Dpn II GATC
Dra III CACNNNGTG
Drd I1 GACN6GTC
Eae I YGGCCR
Ear I CTCTTC
Eci I2 GGCGGA
EcoR I2 GAATTC
EcoR V GATATC
Fnu4H I GCNGC
Hinc II1 GTYRAC
Hinf I GANTC
Hpa I2 GTTAAC
Hpy188 III TCNNGC
Mbo I GATC
MspA1 I CMGCKG
Mwo I2 GC(N7)GC
Nci I CCSGG
Nhe I GCTAGC
Nla IV GGNNCC
Ple I2 GAGTC
Pme I GTTAAAC
PshA I2 GACNNNNGTC
Rsa I2 GTAC
SaI I GTCGAC
Sau3A I GATC
Sau96 I GGNCC
SfaN I2 GCATC
Sfi I GGCC(N5)GGCC
Tfi I2 GAWTC
Tse I2 GCWGC
   

Cleavage Not Blocked at Sites with Overlapping CG
Afl III ACRYGT
Ahd I GAC(N5)GTC
Alw I GGATC
BamH I GGATCC
Ban II GRGCYC
Bbs I GAAGAC
Bbv I GCAGC
BciV I GTATCC
Blp I GCTNAGC
Bme1580 I GKGCMC
BsaJ I CCNNGG
BsaW I WCCGGW
BsaX I AC(N5)CTCC
Bsg I GTGCAG
BsiHKA I GWGCWC
Bsm I GAATGC
BsoB I CYCGRG
Bsp1286 I GDGCHC
BspM I ACCTGC
BssS I CTCGTG
BstE II GGTNACC
BstY I RGATCY
Btg I CCRYGG
EcoO109 I RGGNCCY
Fok I GGATG
Hae III GGCC
Hph I GGTGA
Hpy188 I TCNGA
HpyCH4 III ACNGT
Kpn I GGTACC
Mly I GAGTC
Mnl I CCTC
Msp I CCGG
PflF I GACNNNGTC
PspOM I GGGCCC
Sac I GAGCTC
Sap I GCTCTTC
Sph I GCATGC
Taq I TCGA
Tsp45 I GTSAC
Tth111 I GACN3GTC
Xma I CCCGGG
Xmn I GAA(N4)TTC